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for the record, i know the difference between the pronunciations of Administrator, and adMIN is right, but i still say ADmin, cuz its been the short form for so long, i just say it with the downward inflection because its faster to say.
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genrally speaking, people don't put emphasis on the last syl.
it almost always goes near the beginning of a word.
Someone think of another 2 syl. with the emphasis on the second syl. its rare.
edit: thought of one. degree. deGREE. although i have heard people say DEgree..mostly just scots taht say DEgree though..